Oxidation of iron: the relation between oxidation kinetics and oxide electronic structure |
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| Authors: | Roosendaal Vredenberg Habraken |
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| Institution: | Section Interface Physics, Debye Institute, Utrecht University, P.O. Box 80.000, 3508 TA Utrecht, The Netherlands. |
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| Abstract: | The test of the validity of the Fromhold-Cook theory of metal oxidation for the O2/Fe system in the tunnel regime is impeded by the growth of a passivating Fe2+/Fe3+ double layer at T150 degrees C, the thermionic emission of electrons is rate limiting for oxygen coverages larger than 13x10(15) atoms/cm(2). |
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