Stability of [Co(NH3)6]3+ in nitrobenzene saturated with water |
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| Authors: | E Makrlík P Vaňura |
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| Institution: | (1) Faculty of Education, Charles University, 116 39 Prague, Czech Republic;(2) Prague Institute of Chemical Technology, 166 28 Prague, Czech Republic;(3) Present address: 341 42 Kolinec, Czech Republic |
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| Abstract: | From extraction measurements, the individual extraction constant of the hexamminecobalt (III) cation, Co(NH3)6]3+, in water-nitrobenzene system has been determined
![$$(\log K_{Co(NH_3 )_6 ]3 + }^i = 10.5)$$](/content/f466421t23n2277m/10967_2005_Article_BF02163828_TeX2GIFIE1.gif)
. Further, using known thermodynamic parameters and general relations, the stability constant of the complex Co(NH3)6]3+ in nitrobenzene saturated with water was evaluated for 25 °C in the form log  nb{Co(NH3)6]3+}=54.1. |
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