Kinetics and mechanism of TI(III) oxidation of cellobiose in acidic medium |
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| Authors: | S N Shukla and R N Keserwani |
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| Institution: | (1) Chemistry Department, Lucknow University, Lucknow-7, India |
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| Abstract: | TI(III) oxidation of cellobiose in the presence of H2SO4 in aqueous acetic acid is first order in each reactant and is acid catalyzed. TI(OAc)
2
+
is the active species. Products identified are gluconic acid and glucose. A mechanism consistent with the temperature, solvent, acidity and salt effects is been proposed.
            TI(III)      H2SO4         .   TI(OAc)
2
+
.    .   ,   , , .
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| Keywords: | |
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