Cyclization of o-nitrosoacylbenzenes to anthranils |
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Authors: | S. S. Mochalov T. P. Surikova Yu. S. Shabarov |
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Affiliation: | (1) N. I. Pirogov Moscow State Medical Institute, M. V. Lomonosov Moscow State University, USSR |
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Abstract: | 5-Bromo- and 5-methoxy-3-ethylanthranils, respectively, were obtained by cyclization of o-nitrosopropiophenone under the influence of hydrogen bromide in benzene and hydrogen chloride in methanol. In these reactions, the starting nitroso ketone undergoes redox transformations that also proceed readily in an inert solvent in the absence of any cyclizing reagents.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 886–890, July. 1976. |
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