| THE CONTROL OF POLYMETHACRYLATE MOLECULAR STRUCTURE BY GROUP TRANSFER POLYMERIZATION |
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| 作者姓名： | OWEN W. WEBSTER |
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| 作者单位： | Central Research |
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| 摘 要： | INTRODUCTION Group transfer polymerization (GTP) is a method for controlling the structure of acrylic polymers in which reactive chain ends are covalentiy bound to a trimethylsilyl group. In the presence of a catalyst, monomer inserts into these chain ends between the silyl group and the last monomer unit. The process is illustrated by equation (1) for methyl methacrylate. GTP is a living polymerization, i. e., there is little or no chain termination and no chain transfer. A significant advantage of GTP is that it
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| 收稿时间： | 1988-06-05 |
THE CONTROL OF POLYMETHACRYLATE MOLECULAR STRUCTURE BY GROUP TRANSFER POLYMERIZATION |
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| OWEN W. WEBSTER.THE CONTROL OF POLYMETHACRYLATE MOLECULAR STRUCTURE BY GROUP TRANSFER POLYMERIZATION[J].Chinese Journal of Polymer Science,1990,0(1):1-9. |
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| Authors: | OWEN W WEBSTER |
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| Institution: | Central Research and Development Department; E. I. Du Pont and Company; P.O.Box 80328; Wilmington; Delaware 19880-0328 USA |
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