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Vapor‐Phase Linker Exchange of the Metal–Organic Framework ZIF‐8: A Solvent‐Free Approach to Post‐synthetic Modification |
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| Authors: | Joo Marreiros Lenz Van Dommelen Guillaume Fleury Rodrigo de Oliveira‐Silva Timothe Stassin Paul Iacomi Shuhei Furukawa Dimitrios Sakellariou Philip L Llewellyn Maarten Roeffaers Rob Ameloot |
| Institution: | João Marreiros,Lenz Van Dommelen,Guillaume Fleury,Rodrigo de Oliveira‐Silva,Timothée Stassin,Paul Iacomi,Shuhei Furukawa,Dimitrios Sakellariou,Philip L. Llewellyn,Maarten Roeffaers,Rob Ameloot |
| Abstract: | Zeolitic imidazolate frameworks (ZIFs) are a sub‐class of metal–organic frameworks (MOFs). Although generally stable, ZIFs can undergo post‐synthetic linker exchange (PSLE) in solution under mild conditions. Herein, we present a novel, solvent‐free approach to post‐synthetic linker exchange through exposure to linker vapor. |
| Keywords: | Dampfphasen-Linkeraustausch Lö sungsmittelfreie Modifikationen Metall-organische Gerü ste ZIF-8 ZIFs mit gemischten Linkern |