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Bimetal‐Catalyzed Cascade Reaction for Efficient Synthesis of N‐Isopropenyl 1,2,3‐Triazoles via In‐Situ Generated 2‐Azidopropenes |
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| Authors: | Zhenhua Liu Wenjing Hao Zhixian Liu Wen Gao Zhihai Zhang Yanan Zhang Xiang Li Lili Tong Bo Tang |
| Abstract: | A bimetal‐catalyzed cascade reaction for the synthesis of N‐isopropenyl 1,2,3‐triazoles in high yield is reported. This reaction involves the generation of 2‐azidopropenes in situ by C(sp3)‐OAr bond cleavage for click reaction and features a broad substrate scope, good functional group tolerance and readily available substrates. |
| Keywords: | 1 2 3-triazoles alkynes bimetal-catalyzed click reaction vinyl azides |