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Photo‐Powered Collapse of Supramolecular Polymers Based on an Overcrowded Alkene Switch
Authors:Jing‐Jing Yu  Wen‐Jing Liang  Qi Zhang  Ming‐Ming Li  Da‐Hui Qu
Abstract:A supramolecular polymer was constructed from a light‐driven overcrowded alkene switch modified with two alkylated gallic acid amide pendants ( MSP‐1 ). Upon UV irradiation, stable MSP‐1 isomerized into unstable MSP‐2 , which induced the effective collapse of well‐defined cross‐linked supramolecular polymers, and the reassembly can be realized by aging at low temperature.
Keywords:overcrowded alkene switch  photo-responsive  self-assembly  supramolecular polymer
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