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Rhodium‐Catalyzed C−H Activation Enabled by an Indium Metalloligand |
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| Authors: | Ryosuke Yamada Nobuharu Iwasawa Jun Takaya |
| Abstract: | Rhodium complexes with an indium metalloligand were successfully synthesized by utilizing a pyridine‐tethered cyclopentadienyl ligand as a support for an In?Rh bond. The indium metalloligand dramatically changes the electronic and redox properties of the rhodium metal, thereby enabling catalysis of sp2C?H bond activation. |
| Keywords: | C-H-Aktivierung Indium Metalloliganden Rhodium Z-Liganden |