Stable Perovskite Quantum Dots Coated with Superhydrophobic Organosilica Shells for White Light‐Emitting Diodes

Metalammonium lead perovskite (MAPbX₃, MA=CH₃NH₃⁺; X=Cl, Br, I) quantum dots (QDs) have attracted tremendous attention due to their outstanding optical properties. However, they usually suffer from poor stability towards water or moisture, which seriously limits their practical applications. Here, we report a simple and effective approach to improve the stability of MAPbBr₃ QDs by encapsulating them with superhydrophobic fluorinated organosilica (FSiO₂) shells. The water‐resistant stability of the superhydrophobic MAPbBr₃ QDs/FSiO₂ is significantly enhanced and they display strong fluorescence even after immersion in water for 12 hours. This method is readily extended to prepare superhydrophobic MAPbBr_2.4Cl_0.6 QDs/FSiO₂ and MAPbI₃ QDs/FSiO₂ powders. These superhydrophobic MAPbX₃ QDs/FSiO₂ can be further used to fabricate white light‐emitting diodes (LEDs) with comparable color to pure white emission.