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Copper‐Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes |
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| Authors: | Zheng‐Li Liu Chao Yang Qi‐Yan Xue Meng Zhao Cui‐Cui Shan Yun‐He Xu Teck‐Peng Loh |
| Abstract: | A copper‐catalyzed silylation of propargyl dichlorides was developed to access chloro‐substituted allenylsilanes under mild reaction conditions. Moreover, enantioenriched chloro‐substituted allenylsilanes can be synthesized in moderate to high yields and good enantioselectivities with this protocol. |
| Keywords: | Allene Kupfer Enantioselektivitä t Silane Synthesemethoden |