A new Chloride-Selective Carrier and its Evaluation in Ion-Selective Electrodes |
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Authors: | Katerina Perdikaki John K Tsagatakis Nikolas A Chaniotakis |
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Institution: | (1) Laboratory of Analytical Chemistry, Department of Chemistry, University of Crete, 71 409 Iraklion Crete, Greece, GR |
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Abstract: | A new chloride selective carrier, the tributyltin cinnamate, is evaluated for its analytical characteristics when incorporated
in liquid polymeric membranes of ion-selective electrodes. The electrode constructed based on this carrier exhibited an improved
selectivity towards chloride as compared to those based on the existing chloride carriers, completely satisfying the selectivity
for direct blood measurements. Additionally, the response time of the sensor is fast, while the good signal stability allows
for the application as a stand-alone device or as a detector in FIA system. The electrode exhibited analytical characteristics
suitable for its employment in a variety of real-sample analysis. |
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Keywords: | : ISE tributyltin cinnamate chloride-selective carrier |
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