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Hydrogen absorption property and magnetism of SmFeAl and its hydrides
Authors:Yuntao Wang  Huaiyu Shao  Xingguo Li  Lefu Zhang  Seiki Takahashi
Institution:1. The State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871, China;2. Faculty of Engineering, Department of Materials Science and Engineering, Iwate University, 4-3-5 Ueda, Morioka, 020-8551, Japan
Abstract:Magnetic properties of SmFeAl and its hydrides synthesized at 298–673 K under 40 bar hydrogen pressure were investigated by a superconducting quantum interference device (SQUID) from 4.2 to 300 K. SmFeAl and its hydrides have a mictomagnetic transition during the field-cooled process. In both SmFeAl and its hydrides, a shifted magnetic hysteresis cycle towards positive magnetization was observed. But when SmFeAlHx decomposes completely into SmHx and Fe–Al alloy, this special transition disappears.
Keywords:SmFeAl compound  Hydrogen absorption  Hydrides  Mictomagnetism  Field-induced magnetic transition
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