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Crystallographic and magnetic properties of (Nd,Dy)3Fe27.5(Ti,Mo)1.5 compounds
Authors:SB Han  XF Liu  JY Lv  J Peng  YM Hao  XJ Li  DF Chen  YJ Xue  JH Li  ZB Hu
Institution:1. College of Chemistry and Chemistry Engineering, Graduate School of Chinese Academy of Science, Beijing 100049, China;2. China Institute of Atomic Energy, Beijing 102413, China
Abstract:A systematic study of the formation, structure and magnetic properties of (Nd,Dy)3Fe27.5(Ti,Mo)1.5 compounds has been performed. Rietveld analyses of the X-ray patterns of the samples indicate that the concentrations of Ti and Mo affect the formation and structural properties slightly, whereas different rare-earth (Nd and Dy) contents influence them significantly. It is found that high Dy contents make it difficult to form the 3:29-type structures. The Curie temperatures of Nd2.1Dy0.9Fe27.5Ti1.5−xMox decrease monotonically as more Ti was replaced by Mo but their saturation magnetizations remain almost unchanged; in contrast, for Nd3−yDyyFe27.5TiMo0.5, their saturation magnetizations decrease monotonically with increasing Dy contents while their Curie temperatures are constant.
Keywords:75  50  Ww  61  66  Dk  61  10  Nz
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