Surface magnetic phase transitions in films

Using a simple Landau model, we discuss the different possibilities of generating magnetic effects at a second-order transition for films. Varying the sample size d$d$ and/or surface coupling γ$\gamma$ one can decrease or increase substantially the surface critical temperature _Ts$T_{\mathrm{s}}$ and the saturation magnetization _Ms$M_{\mathrm{s}}$. In the case of γ>0$\gamma >0$, _Ms$M_{\mathrm{s}}$ and _Ts$T_{\mathrm{s}}$ decrease from the bulk values as the film thickness is reduced. These theoretical results are in nice agreement with the experimental data on superconducting _MgB2${\mathrm{MgB}}_2$ thin films. By contrast, for γ<0$\gamma <0$, an enhancement of both quantities is expected. This extraordinary transition has rarely been observed experimentally and, usually, the situation is far from being clear. We analyze a new experiment on _NiFe2O4${\mathrm{NiFe}}_2{\mathrm{O}}_4$ ultra-thin films, where a very strong enhancement of the saturation magnetization is observed.