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Electroanalytical study of the kinetics of thefac-mer isomerization of [ReCl(CO)3(PMe2Ph)2]+ in acetonitrile |
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| Authors: | Renato Seeber Gian Antonio Mazzocchin Edoardo Roncari Ulderico Mazzi |
| Institution: | (1) Istituto di Chimica Generale dell'Università, Pian dei Mantellini 44, 53100 Siena, Italy;(2) Laboratorio di Chimica e Tecnologia dei Radioelementi del C.N.R., Area della Ricerca, Corso Stati Uniti 5, 35100 Padova, Italy |
| Abstract: | Summary The isomerization offac-ReCl(CO)3(PMe2Ph)2]+ to the corresponding meridional-trans isomer has been studied by electroanalytical techniques in MeCN solvent. Chronoamperometric and cyclic voltammetric data relative to the oxidation offac- andmer-ReCl(CO)3(PMe2Ph)2] allow the accurate determination of the very high kinetic rate constant for the isomerization and permit discussion of thermodynamic aspects of redox homogeneous chemical reactions involving species of the different redox couples arising from the anodic processes. |
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