Ligand-free Ni-catalyzed reductive cleavage of inert carbon-sulfur bonds |
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| Authors: | Barbero Nekane Martin Ruben |
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| Affiliation: | Institute of Chemical Research of Catalonia (ICIQ), Av Pa?sos Catalans 16, 43007, Tarragona, Spain. |
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| Abstract: | A catalytic reductive cleavage of C(sp(2))- and C(sp(3))-SMe bonds under ligandless conditions is presented. The method is characterized by its wide scope and high chemoselectivity profile including challenging substrate combinations, allowing the design of orthogonal and site-selectivity approaches. |
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