All-cis-retinal and 7-cis,9-cis,11-cis-retinal1 |
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| Affiliation: | 1. Department of Primary Child Health Care, Children''s Hospital of Chongqing Medical University, Chongqing, P.R. China;2. Ministry of Education Key Laboratory of Child Development and Disorders, Chongqing, P.R. China;3. China International Science and Technology Cooperation base of Child development and Critical Disorders, Chongqing Key Laboratory of Pediatrics, Chongqing, P.R. China;4. Department of Nutrition, Southwest Hospital, Third Military Medical University, Chongqing, P.R. China;5. Clinical Psychology Department, Children''s Hospital of Chongqing Medical University, Chongqing, P.R. China;6. Children''s Nutrition Research Center, Chongqing, P.R. China |
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| Abstract: | A modified 15 + 5 route led to 7-cis,9-cis,11-cis-retinonitrile in high selectivity and also a lesser amount of all-cis-retinonitrile. DIBAL reduction gave the corresponding retinal isomers. The absorption maximum 287nm of all-cis-retinal reveals the distorted nature of the chromophore. |
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