Palladium-Catalyzed Reaction of 1,3-diene monoepoxides with sodium azide. 1,4-Azidohydroxylation of conjugated dienes. |
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| Affiliation: | 1. Institute of Radiochemistry and Experimental Molecular Imaging, University Clinic Cologne, Kerpener Str. 62, 50937 Cologne, Germany;2. Institute of Neuroscience and Medicine, INM-5: Nuclear Chemistry, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany;3. Max Planck Institute for Metabolism Research, Gleueler Str. 50, 50931 Cologne, Germany;1. Department of Chemistry, National Institute of Technology, Tiruchirappalli, 620015, India;2. Department of Chemistry, Siddha Central Research Institute (SCRI), Arumbakkam, Chennai, 600106, India;3. WESTChem School of Chemistry, University of Glasgow, Glasgow, G12 8QQ, Scotland, United Kingdom;1. Beijing National Laboratory for Molecular Science (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;3. National Engineering Research Center for Carbohydrate Synthesis, Jiangxi Normal University, Nanchang 330022, China;1. McDonald Institute for Archaeological Research (University of Cambridge), Downing St., CB2 3ER, Cambridge, United Kingdom;2. Leibniz-Laboratory for Radiometric Dating and Isotope Research (University of Kiel), Max-Eyth-Str. 11-13, 24118 Kiel, Germany;3. AG Systematic Proteome Research & Bioanalytics, Institute for Experimental Medicine (University of Kiel), Niemannsweg 11, 24105, Kiel, Germany;1. Department of Chemistry, Indian Institute of Engineering Science and Technology, Shibpur, Howrah, 711 103, West Bengal, India;2. Department of Chemistry, Nistarini College, Purulia, 723101, West Bengal, India;3. Department of Chemistry, Memorial University of Newfoundland, St. John''s, NL, A1B 3X7, Canada;4. Department of Chemistry and Biochemistry, Wilfrid Laurier University, 75 University Ave W, Waterloo, ON, N2L 3C5, Canada |
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| Abstract: | Palladium-catalyzed regioselective 1,4-addition of sodium azide to vinylepoxides afford 4-azido-2-alkenols in good yields. |
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