Barbier-type reaction with trialkylstibine 1 |
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| Affiliation: | 1. State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, PR China;2. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, 266042, PR China;1. School of Chemistry and Chemical Engineering, State of Key Laboratory of Coordination, Nanjing University, Nanjing 210093, China;2. Institute for Chemistry & BioMedical Sciences, Nanjing University, Nanjing 210093, China;3. High-Tech Research Institute of Nanjing University, Changzhou 213164, China;4. Department of Organic Chemistry I, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel Lardizábal 3, 20018 San Sebastián, Spain;5. IKERBASQUE, Basque Foundation for Science, Alameda Urquijo 36-5, Plaza Bizkaia, 48011 Bilbao, Spain;1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201814, China;2. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 201814, China |
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| Abstract: | In the presence of trialkylstibine, various aldehydes react readily with allyl halides to form homoallylic alcohols in excellent yield. |
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