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A new synthesis of polycyclic aromatic hydrocarbons via titanium(IV)-catalyzed aldol-type condensation of silyl enol ethers with 2-arylacetaldehydes
Institution:1. Department of Mechanical Engineering, KAIST, Daejeon 305-701, Republic of Korea;2. Fuel Cell Vehicle Team 1, Eco-Technology Center, Research & Development Division, Hyundai-Kia Motors Company, Yongin-si, Gyeonggi-do 446-716, Republic of Korea;1. Department of Chemistry, Sungkyunkwan University, Suwon 440-746, Republic of Korea;2. Department of Information Display, Hongik University, Seoul 121-791, Republic of Korea;1. Centre for Organic Photonics & Electronics, The University of Queensland, Brisbane, Australia;2. Institute of Materials Research and Engineering (IMRE), Research Link, Singapore;1. Department of Polymer Engineering, Pukyong National University, Busan 48547, South Korea;2. Department of Materials Chemistry and Engineering, Konkuk Univerisity, Seoul 05029, South Korea;2. Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China;1. Laser and Nonlinear Optics Lab, Department of Physics, National Institute of Technology Calicut, Kerala 673601, India;2. Department of Chemistry, University of Calicut, Kerala 673 635, India
Abstract:A novel one-pot synthesis of angular polycyclic hydrocarbon ring systems involving Ti(IV)-catalyzed aldol-type condensation of silyl enol ethers with 2-arylacetaldehydes and cyclization of the adducts is described.
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