Fvp of bis- and tris-(pyrazol-1-yl)methane. A radical reaction |
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| Institution: | 1. College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, Jiangsu Province 210009, PR China;2. School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, Jiangxi 330063, PR China;3. State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, PR China;1. CAS Key Lab for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences (CAS), Beijing 100049, China;2. University of Chinese Academy of Sciences, Beijing 100049, China |
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| Abstract: | Flash vacuum pyrolysis of bis- and tris-(pyrazol-1-yl) methane was carried out. Alpha, gamma and radical eliminations were considered. The products actually formed correspond to a radical reaction. In the case of bis-(pyrazol-1-yl) methane, working at higher temperatures, pyrimidine was obtained. This compound is formed by rearrangement of a PzCH2 radical. |
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