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Synthesis of a chiral dioxo-cyclam derived from L-phenylalanine and its application to olefin oxidation chemistry
Institution:1. School of Chemistry and Chemical Engineering, Fuyang Normal University, Fuyang, 236041, China;2. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, China;1. School of Chemistry and Chemical Engineering, Fuyang University, Fuyang 236041, China;2. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China;1. College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China;2. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China;3. College of Science, Nanjing Forestry University, Nanjing 210037, China;4. Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstrasse 15, D-76131 Karlsruhe, Germany
Abstract:An optically active dioxo-cyclam macrocycle bearing two benzyl side chains derived from phenylalanine has been synthesized; its Ni(II) complex catalyzes the oxidation of olefins using hypochlorite under phase transfer conditions.
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