Generation and carbonyl addition reactions of Z-dilithiohex-3-ene-1,5-diyne |
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Affiliation: | Department of Chemistry, Yale University, New Haven Connecticut 06511 Usa |
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Abstract: | The reaction of the title dilithio salt with carbonyl compounds leads to products bearing substructures found in recently discovered enediyne antibiotics. The bis condensation product with benzaldehyde undergoes a novel cycloaromatization reaction. |
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