Cyclointercalands.- Incorporation of the phenazine group and of metal binding subunits into macrocyclic receptor molecules. |
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| Institution: | 1. LAAS-CNRS, University of Toulouse, 7 Avenue Du Colonel Roche, 31031 Toulouse, France;2. LCC-CNRS, University of Toulouse, 205 Route de Narbonne, 31077 Toulouse, France;3. CEMES-CNRS, University of Toulouse, 29 Rue Jeanne Marvig, 31055 Toulouse, France;4. Centre de Microcaractérisation Raimond CASTAING, University of Toulouse, CNRS, UT3-Paul Sabatier, INP, INSA, Espace Clément Ader, 3 Rue Caroline Aigle, 31400 Toulouse, France;5. CIRIMAT, University of Toulouse, CNRS, UT3-Paul Sabatier, 118 Route de Narbonne, 31062 Toulouse, France;6. Department of Materials Science and Engineering, University of Texas at Dallas, Richardson, TX, USA;1. Laboratory of Medicinal Chemistry, Endocrinology and Nephrology Unit, CHU de Québec – Research Center (CHUL, T4) and Faculty of Medicine, Université Laval, Québec City, QC, Canada;2. Département de Chimie, Institut de Biologie Intégrative et Des Systèmes (IBIS), and Centre de Recherche sur la Fonction, la Structure et l''Ingénierie des Protéines (PROTEO), Université Laval, Québec City, QC, Canada;3. Département de Biochimie Microbiologie et Bio-informatique, Institut de Biologie Intégrative et des Systèmes (IBIS), and Centre de Recherche sur la Fonction, la Structure et l''Ingénierie des Protéines (PROTEO), Université Laval, Québec City, QC, Canada;1. Department of Food Science and Technology, National Fisheries University, 2-7-1 Nagata-honmachi, Shimonoseki, Yamaguchi, 759-6595, Japan;2. Fukuoka Institute of Health and Environmental Sciences, Mukaizano 39, Dazaifu, Fukuoka, 818-0135, Japan;3. Faculty of Sports and Health Science, Fukuoka University, Fukuoka, 814-0180, Japan;4. Japan Food Research Laboratories, 6-11-10 Nagayama, Tama, Tokyo, 206-0025, Japan;1. Faculty of Chemistry, VNU University of Science, Vietnam National University, Hanoi, 100000 Vietnam;2. Department of Pharmaceutics and Pharmaceutical Technology, Faculty of Pharmacy, Thai Nguyen University of Medicine and Pharmacy, Thai Nguyen City, Vietnam;3. Faculty of Science, Peoples Friendship University of Russia (RUDN University), 117198 Moscow, Russian Federation;4. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation |
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| Abstract: | Macrocyclic receptor molecules containing two phenazine groups 1, or combining a phenazine unit and a metal ion binding site, 2 and 3, have been synthesized; evidence has been obtained for the binding of anionic substrate to the bis-N-methylated 1-Me22+ and of metal ions (Ag+, Cu+) to 2 and 3. |
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