Triplex-catalyzed diels-alder and [2+2] cycloaddition reactions of enol ethers and ketene acetals |
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Affiliation: | 1. Institute of Environmental Research (INFU), Department of Chemistry and Chemical Biology, Chair of Environmental Chemistry and Analytical Chemistry, TU Dortmund, Otto-Hahn-Str. 6, 44221 Dortmund, Germany;2. Department of Chemistry, University of Botswana, Private Bag 0022, Gaborone, Botswana;3. Georg-August University Göttingen, Institute for Organic and Biomolecular Chemistry, Tammannstraβe 2, D-37077 Göttingen, Germany;1. Shanghai Key Laboratory of New Drug Design & School of Pharmacy, East China University of Science and Technology, Shanghai 200237, PR China;2. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, PR China;1. Laboratorio de Biología Celular y Productos Naturales, Edificio de Posgrado, Primer Piso, Escuela Nacional de Medicina y Homeopatía (ENMH), Instituto Politécnico Nacional, Guillermo Massieu Helguera 239, Col. La Escalera Del. Gustavo A. Madero, 07320 CDMX, Mexico;2. Departamento de Química Orgánica, Escuela Nacional de Ciencias Biológicas (ENCB), Instituto Politécnico Nacional, Prolongación de Carpio y Plan de Ayala s/n, Col. Santo Tomás, 11340 CDMX, Mexico;1. College of Humanities and Sciences, Nihon University, Setagaya-ku, Tokyo, 156-8550, Japan;2. Department of Pharmacy, Iryo Sosei University, Chuodai Iino, Iwaki City, Fukushima, 970-8551, Japan;3. School of Pharmacy, Nihon University, 7-7-1 Narashinodai, Funabashi, Chiba, 274-8555, Japan |
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Abstract: | Irradiation of benzene solutions containing a cyanoarene sensitizer, 1,3-cyclohexadiene, and a trimethylsilyl enol ether or ketene acetal leads to intermolecular [4+2] and [2+2] cycloaddition products. |
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