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Coupling of aryl Grignard reagents by electron transfer to 2,3-dichloropropene
Affiliation:1. NEQC: Núcleo de Estudos em Química Computacional, Department of Chemistry, Federal University of Juiz de Fora, Campus Universitário Martelos, 36.036-900 Juiz de Fora, MG, Brazil;2. NQTCM: Núcleo de Química Teórica e Computacional de Macaé, Polo Ajuda, Federal University of Rio de Janeiro, Campus UFRJ-Macaé, 27.971-525 Macaé, RJ, Brazil;3. GQAQ: Grupo de Química Analítica e Quimiometria, Department of Chemistry, Federal University of Juiz de Fora, Campus Universitário Martelos, 36.036-900 Juiz de Fora, MG, Brazil
Abstract:A general synthesis of symmetrical biaryls in good to excellent yields via homo-coupling of aryl Grignard reagents in the presence of 2,3- dichloropropene is described.
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