A novel synthesis of 4-alkyl-4-(4-methoxyphenyl)cyclohex-2-en-1-ones and the Sceletium alkaloid,o-methyljoubertiamine.期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

A novel synthesis of 4-alkyl-4-(4-methoxyphenyl)cyclohex-2-en-1-ones and the Sceletium alkaloid,o-methyljoubertiamine.

Affiliation:	1. Institut für Festkörperphysik, Technische Universität Berlin, Hardenbergstraße 36, 10623, Berlin, Germany;2. Department Physik, Friedrich-Alexander-Universität Erlangen-Nürnberg, Staudtstraße 7, 91058, Erlangen, Germany;3. Institute of Organic Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17 and Center for Materials (LaMa) Justus Liebig University, Heinrich-Buff-Ring 16, 35392, Giessen, Germany;4. Department of Organic Chemistry, Kiev Polytechnic Institute, pr. Pobedy 37, 03056, Kiev, Ukraine

Abstract:	The dianion formed by reduction of (η⁶:η⁶-4,4′-dimethoxybiphenyl)[Cr(CO)₃]₂ reacts with electrophiles such as methyl or ethyl triflate or allyl tosylate at −78 °C followed by CF₃CO₂H and I₂ to form 4-alkyl-4-(4-methoxyphenyl)cyclohex-2-en-1-ones.

Keywords:
本文献已被 ScienceDirect 等数据库收录！