Group selective reduction of acetals related to the ansa chain of the streptovaricins: Conformational and stereochemical analysis |
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| Institution: | Sterling Chemistry Department Yale University, New Haven, Connecticut 06511 U.S.A.;Yale Chemical Instrumentation Center New Haven, Connecticut 06511 U.S.A. |
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| Abstract: | The group selective reductive cleavage of benzylidene acetals derived from diols containing chains equipped with a central chirotopic, nonstereogenic carbon atom is reported. The stereochemistry that is obtained at the central carbon is suitable for application to the synthesis of members of the streptovaricin class of antibiotics. |
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