Intramolecular oxime olefin cycloadditions. Stereospecific formation of functionalized pyrrolidines. |
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| Affiliation: | 1. Università degli Studi di Firenze, Firenze, Italy;2. NFMLab-DCMIC, Politecnico di Milano, Milano, Italy |
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| Abstract: | Allylamines possessing a properly positioned aldoxime or ketoxime chain undergo thermally induced dipolar cycloaddition to bicylic isoxazolidines, with stereospecific introduction of three stereo centers. This provides an entry into stereospecifically functionalized pyrrolidines. |
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