Synthetic studies on oxetanocin,a novel nucleoside with an oxetane ring synthesis of some chiral D-oxetanosyl acylates |
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| Institution: | 1. Universidade Federal de Minas Gerais, Belo Horizonte, MG, Brazil;4. Universidade Federal de Viçosa, Viçosa, MG, Brazil |
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| Abstract: | Some chiral D-oxetanosyl acylates, promising synthetic precursors of oxetanocin, have been synthesized from D-glucose as well as from cis-2-buten-1,4-diol, wherein the most important step requires Baeyer-Villiger oxidation of the carbonyl group attached to C1-position of the corresponding oxetanes. |
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