Marine toxins. Synthesis of the spiro-benzoquinonefuran unit in stypoldione |
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| Affiliation: | 1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, PR China;2. University of Chinese Academy of Sciences, Beijing 100039, PR China;3. Synfuels China Co. Ltd., Taiyuan 030032, PR China |
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| Abstract: | A synthesis of the unusual spiro-benzoquinonefuran unit (13) presentin the marine toxin stypoldione (1), using the strategy (9) → (10) → (12) → (13), is described. |
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