Activation of reducing agents. Sodium hydride containing complex reducing agents 25. A one pot one reagent cross-coupling reaction of aryl halides |
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| Affiliation: | 1. State Key Laboratory of Natural Medicines, Jiangsu Key Laboratory of Drug Discovery for Metabolic Diseases, Center of Drug Discovery, China Pharmaceutical University, Nanjing 210009, PR China;2. Key Laboratory of Regenerative Biology and Institute of Chemical Biology, Guangzhou Institutes of Biomedicine and Health, Chinese Academy of Sciences, Guangzhou 510530, PR China;1. Institute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163, 1060 Vienna, Austria;2. Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford St, Cambridge, MA 02138, USA;3. Medicines Research Centre, GlaxoSmithKline, Gunnel''s Wood Road, Stevenage, Herts SG1 2NY, United Kingdom;1. Catalytic Processes and Materials, MESA+ Institute for Nanotechnology, University of Twente, Enschede 7500AE, The Netherlands;2. Aalto University, School of Chemical Technology, Department of Biotechnology and Chemical Technology, P.O. Box 16100, 00076 Aalto, Finland;1. Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche e Ambientali (CHIBIOFARAM), Polo Universitario SS. Annunziata, Università di Messina, Viale Annunziata, I-98168, Messina, Italy;2. Center for Retrovirus Research and College of Pharmacy, The Ohio State University, Columbus, OH, 43210, USA;3. Division of Medicinal Chemistry and Pharmacognosy, College of Pharmacy, The Ohio State University, Columbus, OH, 43210, USA;1. Tohoku Pharmaceutical University, 4-4-1, Komatsushima, Aoba-ku, Sendai, Miyagi 981-8558, Japan;2. Kobe Pharmaceutical University, 4-19-1 Motoyama Kitamachi, Higashinada-ku, Kobe 658-8558, Japan;3. Graduate School of Pharmaceutical Sciences, Kyushu University, 3-1-1 Maidashi, Higashi-ku, Fukuoka 812-8582, Japan;4. Daiichi University of Pharmacy, 22-1 Tamagawa-cho, Minami-ku, Fukuoka 815-8511, Japan |
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| Abstract: | The preparation of NiCRA [NaH-AtmONa-Ni(OAc)2] in the presence of 2,2′-bipyridyl and KI leads to a reagent (termed NiCRA-bpy-KI) which is shown to be one of the most efficient Ni containing reagents reported so far for the cross-coupling of aryl halides. |
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