The absence of ethylenedione in photochemical biscarbonylation reactions |
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| Affiliation: | 1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, PR China;2. University of Chinese Academy of Sciences, Beijing 100039, PR China;3. Synfuels China Co. Ltd., Taiyuan 030032, PR China;1. Department of Chemistry, University of Isfahan, Isfahan 81746-73441, Iran;2. Young Researchers and Elite Club, Islamic Azad University, Shahrekord Branch, Shahrekord, Iran |
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| Abstract: | Photolyses of a number of bridged cyclohexenediones and vinylcyclobutanediones in argon or xenon matrices at 10 K at a variety of wavelengths produced carbon monoxide with no evidence for formation of ethylenedione, the elusive dimer of CO. |
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