Unexpected affects of Me3Si-X on reactions of higher order cyanocuprates期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Unexpected affects of Me3Si-X on reactions of higher order cyanocuprates

Institution:	1. Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation;2. Novosibirsk State University, st. Pirogova 2, 630090, Novosibirsk, Russian Federation;3. Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry RAS, pr. Staromonetny 35, 119017 Moscow, Russian Federation;4. Moscow State University, Leninskie Gory 1, 119991, Moscow, Russian Federation;5. Department of Applied Chemistry, Public University of Navarra, 31006 Pamplona, Spain;6. Department of Inorganic Chemistry, University of Salamanca, Salamanca, Spain

Abstract:	The assumed compatibility of Me₃SiCl with higher order cyanocuprates has been studied by both chemical and spectroscopic (¹H, ⁷Li, ²⁹Si NMR) means. Both types of experiments confirm that Me₃Si-X significantly alters the composition of both homo (R₂Cu(CN)Li₂) and mixed (RR′Cu(CN)Li₂) reagents.

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