Enantioselective total synthesis of the pumiliotoxin a alkaloids via reductive iminium ion-alkyne cyclizations. Total synthesis of (+)-pumiliotoxin a |
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Affiliation: | 1. SRM Research Institute, SRM Institute of Science and Technology, Kattankulathur, Chennai, Tamil Nadu 603203, India;2. Kalaslingam Academy of Research and Education, Krishnan Kovil, Tamil Nadu 626126, India |
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Abstract: | A highly practical new route for the enantioselective synthesis of the pumiliotoxin A alkaloids in which the title reaction is a key step is disclosed. |
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