Synthesis from D-glucose of alexine [(1R,2R,3R,7S,8S)-3-hydroxymethyl-1,2,7-trihydroxypyrrolizidine], 3-epialexine and 7-epialexine |
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| Institution: | 1. Dyson Perrins Laboratory, Oxford University, South Parks Road, Oxford OX1 3QY U.K.;2. Jodrell Laboratory, Royal Botanic Gardens, Kew, Richmond, Surrey TW9 3DS U.K.;1. Yildiz Technical University, Faculty of Science and Letters, Department of Physics, 34210 Esenler, Istanbul, Turkey;2. Istanbul Technical University, Faculty of Science and Letters, Department of Physics Engineering, 34469 Maslak, Istanbul, Turkey;1. Marmara University School of Medicine, Department of Pediatrics, Division of Pediatric Infectious Diseases, Istanbul, Turkey;2. Marmara University School of Medicine, Department of Pediatrics, Division of Pediatric Intensive Care Unit, Istanbul, Turkey;3. Marmara University School of Medicine, Department of Anesthesiology and Reanimation, Istanbul, Turkey;4. Marmara University School of Medicine, Department of Biochemistry, Istanbul, Turkey;5. Marmara University School of Medicine, Department of Pediatrics, Division of Pediatric Endocrinology, Istanbul, Turkey;6. Marmara University School of Medicine, Department of Microbiology, Istanbul, Turkey;1. Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation;2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation;3. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991 Moscow, Russian Federation;1. Graduate School of Pharmacy Pharmaceutical Sciences, Faculty of Pharmacy and Pharmaceutical Sciences, Fukuyama University, Fukuyama, Hiroshima 729-0292, Japan;2. Faculty of Pharmaceutical Sciences, Health Sciences University of Hokkaido, Ishikari-Tobetsu, Hokkaido 061-0293, Japan |
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| Abstract: | A protected 2-azido-2-deoxymannose is a key intermediate in the synthesis of alexine (1R,2R,3R,7S,8S)-3-hydroxymethyl-1,2,7-trihydroxypyrrolizidine], 3-epialexine and 7-epialexine from D-glucose. |
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