An enantioselective approach to chiral pseudoguaianolide intermediates |
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| Affiliation: | 1. Waseda Institute for Advanced Study, Waseda University, 513 Wasedatsurumakicho, Shinjuku, Tokyo 162-0041, Japan;2. Department of Applied Chemistry, Waseda University, 513 Wasedatsurumakicho, Shinjuku, Tokyo 162-0041, Japan;1. College of Pharmacy, Gachon University, Incheon, South Korea;2. Indiana University School of Medicine, Indianapolis, IN, United States;1. State Key Laboratory of Toxicology and Medical Countermeasures, Beijing Institute of Pharmacology and Toxicology, Beijing 100850, China;2. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China |
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| Abstract: | The viability of an enantioselective route to pseudoguaianolides has been established with the construction of hydroazulenone 3, whose absolute configuration parallels that of radiatin. |
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