Palladium catalyzed annulation reaction using a bifunctional allylic alkylating agent |
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| Affiliation: | 1. Drug Discovery & Development Center, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, China;2. Zhongshan Institute for Drug Discovery, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Zhongshan 528400, China;3. School of Pharmaceutical Sciences, Southern Medical University, Guangzhou 510515, China;4. Guangzhou Municipal and Guangdong Provincial Key Laboratory of Molecular Target & Clinical Pharmacology, NMPA and State Key Laboratory of Respiratory Disease, Guangzhou Medical University, Guangzhou 511436, Guangdong, China;5. School of Pharmaceutical Science and Technology, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou 310024, China;6. University of Chinese Academy of Sciences, Beijing 100049, China;1. Science and Technology on Scramjet Laboratory, National University of Defense Technology, Changsha, Hunan 410073, People’s Republic of China;2. Hypervelocity Aerodynamics Institute, Chinese Aerodynamics Research and Development Center, Mianyang 621000, People’s Republic of China;1. Department of Nuclear Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea;2. Institute of Nano Science & Technology, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea;1. Departamento de Produtos Farmacêuticos, Faculdade de Farmácia, Universidade Federal de Minas Gerais, Avenida Antônio Carlos, 6627, CEP 31270-901, Belo Horizonte, MG, Brazil;2. Departamento de Química, Instituto de Ciências Exatas, Universidade Federal de Minas Gerais, Avenida Antônio Carlos, 6627, CEP 31270-901, Belo Horizonte, MG, Brazil;3. Departamento de Botânica, Instituto de Ciências Biológicas, Universidade Federal de Minas Gerais, Avenida Antônio Carlos, 6627, CEP 31270-901, Belo Horizonte, MG, Brazil;4. Departamento de Bioquímica e Imunologia, Instituto de Ciências Biológicas, Universidade Federal de Minas Gerais, Avenida Antônio Carlos, 6627, CEP 31270-901, Belo Horizonte, MG, Brazil |
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| Abstract: | Methylene-cyclopentane and -cyclohexane derivatives were synthesized by the reaction of 2-methylene-propane-1,3-diol diacetate with dicarbanions under the palladium catalysis. |
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