Molecular aggregation and its applicability to synthesis. The Diels-Alder reaction |
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Institution: | 1. Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia;2. Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia |
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Abstract: | The rates of intermolecular Diels-Alder reactions involving relatively hydrophobic dienes and dienophiles are significantly increased if these reactions are carried out in ethylene glycol. These rate enhancements are most easily understood in terms of aggregation phenomena. |
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