Synthesis and characterization of a 1-D porous barium carboxylate coordination polymer, [Ba(HBTB)] (H3BTB = benzene-1,3,5-trisbenzoic acid) |
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Authors: | Foo Maw Lin Horike Satoshi Kitagawa Susumu |
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Affiliation: | Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan. |
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Abstract: | The synthesis and characterization of [Ba(HBTB)] is reported. This is the first porous framework synthesized with barium using carboxylate ligands. The framework has robust microporous character (Langmuir surface area of 879 m(2) g(-1)) and possesses unsaturated metal sites when fully desolvated. |
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