Samarium diiodide-induced couplings of carbonyl compounds with methoxyallene leading to 4-hydroxy 1-enol ethers |
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| Authors: | Hölemann Alexandra Reissig Hans-Ulrich |
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| Institution: | Institut für Chemie-Organische Chemie, Freie Universit?t Berlin, Takustrasse 3, D-14195 Berlin, Germany. |
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| Abstract: | A surprising samarium diiodide-induced coupling reaction of carbonyl compounds with methoxyallene provided 4-hydroxy 1-enol ethers, which are versatile synthetic building blocks. In this coupling reaction, methoxyallene serves as an acrolein equivalent, which cannot directly be employed. reaction: see text] |
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