Synthesis and structure of amino acid-derived benziodazoles: new hypervalent iodine heterocycles |
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| Authors: | Zhdankin Viktor V Koposov Alexey Y Su Liansheng Boyarskikh Vyacheslav V Netzel Brian C Young Victor G |
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| Institution: | Department of Chemistry, University of Minnesota-Duluth, Duluth, MN 55812, USA. vzhdanki@d.umn.edu |
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| Abstract: | New N-functionalized benziodazoles were prepared by the peracetic oxidation of 2-iodobenzamides derived from alanine or valine. X-ray crystal structural analysis of two benziodazole-based phenyliodonium derivatives provides insight into facile interchange between benziodazoles and iminium benziodoxoles under acidic or basic conditions. reaction: see text] |
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