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Quantum statistics of reaction-diffusion systems
Authors:C.I. Ivanov
Affiliation:Bulgarian Academy of Sciences, Institute of Organic Chemistry, Laboratory of Quantum Chemistry, Sofia 1113, Bulgaria
Abstract:A strictly quantum-statistical theory of inhomogeneous reactions is presented. The treatment is based on the theory of multi-channel reactive scattering. For the configuration probabilities of the reactants a system of reaction-diffusion equations is obtained. The expressions for the diffusion tensor and the reaction-rate coefficients are established in terms of microscopic parameters characteristic of the reacting species.
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