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Solid State Conductivity and Catalytic Activity of Hexacyanoferrate(II)–Thiosemicarbazide Complexes of 3d-Metals
Authors:Koksharova  T V  Ptashchenko  A A  Masleeva  N V  Fel'dman  S V  Pasternak  N N  Stukalov  S A
Institution:(1) I. I. Mechnikov Odesa National University, 2 Dvoryans'ka Vul., 65026 Odesa, Ukraine
Abstract:The temperature dependence of the resistivity of tablets of hexacyanoferrate(II)–thiosemicarbazide complexes of chromium(III), manganese(II), iron(III), cobalt(III), nickel(II), copper(II), and zinc(II) was measured in the range 20-90 °C. A relationship between the conductivity of a substance and the rate constant for the catalytic decomposition of hydrogen peroxide is established.
Keywords:hexacyanoferrate(II)–  thiosemicarbazide complexes of d-metal  electrical conductivity  catalytic activity  hydrogen peroxide  decomposition
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