Abstract: | The steric structure of four 2-hydro-2-oxo(thio)-1,3,2-dioxaphosphorinane (DOP) molecules has been studied by means of Raman and IR spectroscopy.
A characteristic feature of these compounds is the presence of a hydrogen atom as a "light" exocyclic substituent whose vibration is not mixed with the vibrations of the molecular skeleton.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 420083 Kazan, Tatarstan, Russia. Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 12, pp. 2725–2730, December, 1992. |