| Abstract: | Thermodynamic functions of ten monomeric compounds have been calculated for three temperatures by the statistical method using molecular structural data and vibrational assignments. The ideal gas state entropies at 298.15°K are: maleic anhydride, 71.9; β-propiolactone, 69.1; vinylene carbonate, 70.1; cyclopentadiene, 65.3; diketene, 72.3; cyclopropene, 58.7, vinyl fluoride, 60.4; ethyleneimine, 62.8; butatriene, 71.7; and carbon suboxide, 66.0 cal./deg-mole. The standard free energies and equilibrium constants of formation are also derived by using mostly the published data on the heats of formation of these monomers. |
