|
|||||
|
|
Room‐Temperature Functionalization of N2 to Borylamine at a Molybdenum Complex |
|
| Authors: | Dr Maria F Espada Soukaina Bennaamane Dr Qian Liao Dr Nathalie Saffon‐Merceron Dr Stéphane Massou Dr Eric Clot Dr Noel Nebra Dr Marie Fustier‐Boutignon Dr Nicolas Mézailles |
| Institution: | 1. Laboratoire Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier, CNRS, Toulouse, France;2. Institut de Chimie de Toulouse ICT-FR2599, Université Paul Sabatier, CNRS, Toulouse Cedex, France;3. Institut Charles Gerhardt Montpellier, UMR 5253 CNRS-UM-ENSCM, Université de Montpellier, Montpellier cedex 5, France |
| Abstract: | Intermolecular, stepwise functionalization by BH bonds of a (triphosphine)MoIV–nitrido complex generated by N2 splitting is reported. The imido–hydride and di‐hydride–amido MoIV complexes have been isolated and characterized. Addition of PinBH to the Mo(H)2(N(BPin)2)]+ complex at room temperature results in the liberation of borylamines from the metal center. |
| Keywords: | boranes hydride ligands molybdenum N2 reduction nitride functionalization |