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Short Total Synthesis of Ajoene
Authors:Filipa Silva  Dr. Shaista S. Khokhar  Danielle M. Williams  Dr. Robert Saunders  Dr. Gareth J. S. Evans  Michael Graz  Prof. Dr. Thomas Wirth
Affiliation:1. School of Chemistry, Cardiff University, Cardiff, UK;2. Neem Biotech, Abertillery, UK
Abstract:We describe a short total synthesis of ajoene, a major biologically active constituent of garlic. The instability of allicin as the only other known alternative starting material has led to the development of a reliable procedure for the synthesis of ajoene from simple building blocks that is also suitable for upscale operations.
Keywords:ajoene  allicin  garlic  organosulfur compounds  selenoxide elimination
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