Tunable Chiroptical Properties from the Plasmonic Band to Metal–Ligand Charge Transfer Band of Cysteine‐Capped Molybdenum Oxide Nanoparticles |
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| Authors: | Yiwen Li Dr Jiaji Cheng Jiagen Li Prof Xi Zhu Prof Tingchao He Prof Rui Chen Prof Zikang Tang |
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| Institution: | 1. Department of Electrical and Electronic Engineering, Southern University of Science and Technology, Shenzhen, P. R. China;2. The Institute of Applied Physics and Materials Engineering, University of Macau, Taipa, Macau;3. College of Physics and Energy, Shenzhen University, Shenzhen, P. R. China;4. School of Science and Engineering, The Chinese University of Hong Kong, Shenzhen, P. R. China |
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| Abstract: | Understanding the interactions between a semiconducting nanocrystal surface and chiral anchoring molecules could resolve the mechanism of chirality induction in nanoscale and facilitate the rational design of chiral semiconducting materials for chiroptics. Now, chiral molybdenum oxide nanoparticles are presented in which chirality is transferred via a bio‐to‐nano approach. With facile control of the amount of chiral cysteine molecules under redox treatment, circular dichroism (CD) signals are generated in the plasmon region and metal–ligand charge‐transfer band. The obtained enhanced CD signals with tunable lineshapes illustrate the possibility of using chiral molybdenum oxide nanoparticles as potentials for chiral semiconductor nanosensors, optoelectronics, and photocatalysts. |
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| Keywords: | chiroptics metal– ligand charge transfer molybdenum oxide nanoparticles surface plasmon |
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